Fjölrit RALA - 15.06.2004, Qupperneq 36

Fjölrit RALA - 15.06.2004, Qupperneq 36
Slovakian “Andozem” in the frame of Andosols in Europe J. Balkovic1, B. Juráni2 lSoil Science and Conservation Research Institute in Bratislava 2Department of Soil Science, Faculty ofNatural Science, Comenius University in Bratislava Some volcanic mountains in Slovakia, namely those which are built by Neogene andesite rocks, are somewhere covered by Andosols (“Andozem” in Soil Classification System of Slovakia). The contribution deals with basic characteristics of andic properties of Slovakian profiles in the frame of European Andosols. Moreover it also deals with some specific andic properties aiming to show that andic soils in Slovakia fulfill an assumption for being classified as Andosols. We used four COST profiles of Slovakian volcanic soils (N 21 SK - N 24 SK). They are tentatively classified as Sili-Dystric Andosol (N 21 SK), Sceleti-Dystric Andosol (N 22 SK), Andic Cambisol (N 23 SK) and Fulvi-Sceleti-Dystric Andosol (N 24 SK). Basic classification attributes of studied profiles are summarized in table 1. Table 1 Basic soil properties relevant for describing andic soil profiles Prof. N21 SK N22 SK N23 SK N24 SK Notes: Hor. Corg Sio Alo Alp Feo Fep All. Fer. Pret pH (NaF) BD Colour % % % % % % % % % g.cm3 wet A 10.2 0.35 1.56 1.24 0.32 0.54 1.9 0.6 98.20 10.30 0.66 10YR2/1 Bwl 2.10 0.96 3.28 0.91 0.62 0.02 8.8 1.1 99.74 11.06 0.80 7.5YR4/4 Bw2 0.42 010 0.78 0.27 0.41 0.02 - 0.7 76.33 9.50 1.21 7.5YR4/5 A 10.8 0.04 0.68 0.67 0.98 0.58 0.2 1.7 85.53 7.93 0.69 10YR2/1 A/B 5.85 0.25 1.92 1.96 0.85 0.52 1.0 1.5 98.50 10.88 0.83 5YR 2.5/3 Bw 1.92 0.57 2.07 0.85 0.56 0.03 4.5 1.0 97.33 10.89 0.86 10YR4/4 Ahl 7.20 0.10 0.59 0.54 0.59 0.14 0.50 1.0 65.38 8.96 0.72 10YR2/1 Ah2 4.65 0.05 0.61 0.58 0.58 0.14 0.20 1.0 68.46 9.04 0.78 10YR3/2 Bw 2.55 0.06 0.69 0.51 0.58 0.12 0.70 1.0 69.97 9.43 0.92 10YR4.5/3 Ahl 15.9 0.03 0.39 0.20 0.54 0.30 - 0.9 61.2 7.73 0.73 10YR2/1 Ah2 12.0 0.22 1.23 1.04 0.38 0.05 1.2 0.7 98.4 10.78 0.65 10YR2/2 A/B 8.40 0.44 1.94 1.37 0.31 0.09 2.6 0.5 98.1 11.59 nd 10YR3/2 Bw 6.0 1.18 3.18 0.44 0.21 0.04 10.1 0.4 99.3 11.68 nd 10YR3/3 B/C 0.90 0.86 1.51 0.45 0.05 0.03 5.0 0.1 96.6 11.26 nd 10YR4/4 organic carbon content (Corg), oxalate silica, aluminium and iron (Sio, Alo, Feo), pyrophosphate aluminium and iron (Alo, Feo), allophane 100/[(-5.1(Alo-Alp)/Sio) + 23.5]Sio (All.), ferrihydrite 1.72Fe (Fer.), exchangeable alkalinity in 1N NaF (pH(NaF)), bulk density at field moismre (BD), nd - not determined Described profiles show a variety of andic soils in Slovakia from weakly developed Andic Cambisols (N23SK), through “sil-andic” Andosol (N21SK) ending at well developed Fulvic Andosols (N24SK). This sequence relatively accurately describes the general andic catena in Slovakian volcanic mountains as it is schematically presented in figure 1. We can follow some general geographical rules in distribution of sil-andic and alu-andic horizons in dependence on altitude and precipitation. Selective dissolving extractions indicate that reactive aluminium in sil-andic horizons of Slovakian Andosols shows the Al/Si ratio between 1 and 2.5, what is probably because of allophane like minerals with gibbsite admixture (Balkovic et Bartosová, 2003). Based on the same source we can assume that organically associated reactive A1 prevails in alu-andic soil horizons, where it is accompanied by “opaline” silica. These genetic mles intimately reflect the Al-solubility mechanisms and Al/Si - ion speciation estimated in horizons of Slovakian volcanic soils (Balkovic et Slivková, 2002a). Studied soils have the effective mechanisms for specific anion sorption. Some quantification of these typical andic properties from Slovakia are presented by Balkovic et Slivková (2002b). 23
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