Fjölrit RALA - 15.06.2004, Page 98

Fjölrit RALA - 15.06.2004, Page 98
The quantity of base cations released to the abrasion solution is very low in all the studied horizons (Ca+Mg+Na+K<0.5 emolc/kg), with the lower concentrations in the soils from France and Azores (0.03-0.1 emolc/kg). The only exception is the soil from Hungary, with abnormally high contentent in all the measured cations. The composition of abrasion solution has no relation to the abrasion pH neither to other parameters generally related to the potential fertility of soils like the total reserve of bases (TRB). Only K and Ca in exchange complex are relatively well correlated to their concentration in abrasion solution (r2=0,771 and =0,638 respectively, for most but not all samples). Weathering index of Parker vs abrasion pH in volcanic soils In conclusion, abrasion pH can be interpreted, in a very general way, in terms of weathering or pedogenetic evolution in the soils of volcanic regions and also may serve as a tool to understand the complex processes that frequently occur in these soils (heterogeneity of parent material, burial processes, tephra inputs, polygenesis). Nevertheless, the mentioned complexity can also hmit the use of this single parameter. As the value of abrasion pH depends on the chemical and mineralogical composition of the material, but also on the physicochemical behaviour of the new surfaces created during the grinding process, many of the unusual characteristics observed in the abrasion pH and abrasion solution composition of volcanic soils are to be linked to the special constituents and properties that characterize these soils, in particular their charge properies and the effects that grinding may produce on them. This represents a disadvantage of the method but it may also help to the understanding of the behaviour of these soils and their components when the obtained information is analyzed in detail for each particular soil or horizon. References Grant, W.H., 1969. Abrasion pH, an index of chemical weathering. Clays and Clay Miner. 17:151-155. Ferrari, G.A., and D. Magaldi. 1983. Degree of soil weathering as determined by abrasion pH: Applications in soil study and paleopedology. Pedologie 33:93-104. Parker, A. 1970. An index of weathering for silicate rocks. Geol. Mag. 107:501-504. Price, J.R., and M.A. Velbel. 2003. Chemical weathering indices applied to weathering profiles developed on heterogeneous felsic metamorphic parent rocks. Chem. Geol. 202:397-416. Stevens, R.E., and M.K. Carron. 1948. Simple field test for distinguishing minerals by abrasion pH. Am. Mineralogist 33:31-49. In Grant (1969). 77
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