Rit (Vísindafélag Íslendinga) - 01.06.1984, Side 271

Rit (Vísindafélag Íslendinga) - 01.06.1984, Side 271
PETROGENETIC RELATIONSHIPS 267 analysed and calculated derivative liquid is quite small. The clinopyroxene still dominates the olivine in the fractionate (>71 per cent). Producing these primitive basalts from a Mg poor ankaramite involves the removal of 22—32 per cent of minerals and leaves a liquid amounting to 68—78 wt. per cent of the original material (Jan 10). Ifsome other samples are selected instead ofjan 10 or 26 (e.g. 30, 65, 66, 46) to represent this compositional interval in the crystal fractionation, the misfit is increased and in some cases becomes even unacceptable, using these same fractionating minerals. K, Ti and A1 are especially difficult to account for in these cases. It is thus clear that by subtracting the primitive mafic phenocryst phases of the ankaramites (the wehrlite crystallization minerals) from “ankarami- tic” liquids, more basaltic compositions are easily reached and these have the whole rock chemical characteristics of the mafic rocks of the Jan Mayen rock suite. The wehrlite fractionation, characterized by chromian diopside and Fo rich olivine (~Fo90), is thus a possible process in the early evolution of the magnesian Jan Mayen magmas. As these liquids start to rise from the great depths of the wehrlite conditions, the ankaramite crystallization, characterized by titan-salite and slightly more fayalitic olivine, may apparently take over the fractionation and direct the evolution into the compositional range of the primitive basalt category. III. Crystal fractionation within the basalts The basaltic rocks of the Jan Mayen rock suite are a voluminous group and they show considerable compositional spectra. Crystal fractionation within this group can thus be imitated in various ways guided by chemical characteristics and mineral contents. In the fractionation within the basaltic rocks, the misfit obtained is in numerous cases increased relative to that of the early fractionation. This happens in spite of an increase of mineral phases used in the calculations and in many cases relatively small com- positional variations between “mother liquid and derived liquids”. Here, four examples of fractionation within the basalts will be shown (Tables 43—46). The first one considers fractionation within the ankarami- tic basalts, which are characterized by the absence of plagioclase in nature. Examples two and three consider the more magnesian basalts as (relatively) K poor and K rich groups. The last example considers the possibilities of fractionating within the low-magnesian basalts. Usingjan 26, as the “mother liquid” in the case of fractionation within ankaramitic basalts, the more magnesian ones (Table 43A) may be pro- duced by subtracting a primitive titan-salite and an olivine of F083.5 com- position. This choice of minerals is in reasonable agreement with petro- graphic observations. The total fit is rather poor. The misfit is primarily produced by a lack of A1 and Ca and an excess of the alkalies in the
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Rit (Vísindafélag Íslendinga)

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