Jökull

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Jökull - 01.12.1983, Qupperneq 68

Jökull - 01.12.1983, Qupperneq 68
TABLE 2. C.I.P.W. Norms* of Analysed Lavas and Tephra. TAFLA 2. Reiknuð steindasamsetning í sýnum úr Tóflu 1. S4 S5 S7 S8 S12 S20 S21 S30 S33 S39 Qz 2.8 — _ — — — 0.3 — — 19.1 Or 3.6 4.0 4.0 7.5 2.0 5.3 5.0 6.0 4.9 21.1 Ab 25.0 26.3 26.5 37.2 10.7 22.7 30.3 31.5 27.8 48.6 An 23.5 26.9 27.2 16.9 16.1 21.6 17.8 17.4 21.1 3.8 Ne - - - 0.6 - - - - - — Di 19.5 20.9 21.3 18.9 30.6 21.2 23.6 20.7 21.9 2.9 Hy 12.8 10.5 11.4 - 7.3 12.9 10.7 9.4 9.0 2.0 Ol - 1.7 0.4 12.7 28.4 7.8 - 4.8 5.2 — Mt 5.7 3.8 4.7 1.4 2.7 3.8 5.2 3.0 3.3 2.0 Ilm 6.1 5.2 4.0 4.5 1.8 3.9 6.5 5.8 5.6 0.5 Ap 1.0 0.8 0.7 0.2 0.3 0.7 0.5 1.5 1.2 0.1 An/An+Ab 48.4 50.6 50.6 31.2 60.1 48.8 37.0 35.5 43.2 7.2 Mg/Mg+Fe2+ 66.2 65.2 65.4 50.0 85.1 79.3 63.2 51.6 59.7 24.2 Diff. Ind. 31.4 30.3 30.4 45.4 12.7 28.1 35.6 37.5 32.7 88.8 * Expressed in % cation equivalents and based on analyses recalculated to 100% water-free and with the Fe203/Fe0 ratio adjusted where necessary to an upper limit of Fe203 fixed at %Fe203 = %Ti02+1.5, according to the procedure outlined by Irvine and Baragar (1971). palagonite tuff-breccias and associated cinder cones were briefly observed and sampled to the north- west on Fimmvörðuháls on the eastern flank of the Eyjafjöll volcanic complex. In addition a record of Postglacial volcanic activity emanating from the nearby volcanic centres, especially Katla as de- monstrated by Einarsson et al. (1980), was observed in loessic soil profiles throughout the Sólheimajök- ull area. THE GEOCHEMISTRY OF THE VOLCANIC ROCKS The chemical analyses of selected volcanic rock samples are listed in Table 1 and the corresponding C.I.P.W. norms in Table 2. Further detailed in- formation (petrography, locality, name, etc.) on each rock sample is given in Table 3. These analyses may indicate that there have been changes in the chemistry ofthe magma type erupted over the period of time from the eruption of the oldest rocks in the area (Unit A) to the most recent rocks in the Fimmvörðuháls area. We assume that this period of time was something of the order of two million years. The dominant basalt lava type would appear to have changed from a tholeiitic type in the oldest rocks (Unit A and much of Unit B), to a transitional alkalic type (throughout most of the volcanic succession) with appredably higherNa,O, K20 and TiO, contents and a higher Fe/Mg ratio, to a nepheline-normative alkali olivine basalt type in the most recent volcanic activity in the col area of Fimmvörðuháls. This variation is illustrated on Figure 2 which is a plot of wt.% Na^O + K20 against wt.% SiO, for all analysed lava samples. Sample S12, the lava from Unit A at the foot of Jökulhaus North, is characterised by both high modal and normative olivine contents. It is also distinctly hypersthene normativeand lies well with- in the recognised sub-alkaline i.e. tholeiitic field (MacDonald 1968; Irvine and Baragar 1971) on the alkalies: silica plot. Certainly its lower TiO>, P205, Na20, K20 and Ah Oj contents and lower Fe/Mg ratio contrast with the subsequently erupted volc- anic rocks. On the basis of its chemistry and norma- tive mineralogy it might seem appropriate to classi- fy the rock as a picritic olivine tholeiite but there ís little doubt that it is comparable to other rocks related to the Eyjafjöll volcanic system customarily referred to as ankaramites (Steinþórsson 1964\Jakobs- son 1979). Whilst these authors have indicated that certain of these rocks may be intrusive and also cumulative, the intimate associadon in this instance with related palagonitized brecda indicates an ex- 66 JÖKULL 33. ÁR
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