Greinar (Vísindafélag Íslendinga) - 01.01.1977, Side 95

Greinar (Vísindafélag Íslendinga) - 01.01.1977, Side 95
93 Concerning our case, primary basalt magma, if it formed a fluid layer at an early state of the differentiated earth, could possibly — because of P-T and time conditions — have develop- ed into a state, which cannot be reproduced in laboratory after that state had once disappeared, when it changed into active magma, and flowed to the surface, to turn into crystallized rock — with all the ionic exchanges that crystallization would have caused. This is just a general reminder, not an attempt to escape from solving the problem. In this connection, the importance of shear in crystallization should again be stressed (cf. Chapter 5 and 6). If shear was absent in such a hypothetical fluid basaltic layer, into which state would the fluid change by very slow cooling under high pressure ? In the author’s studies of the Hekla eruption of 1947—48, already quoted, he found reasons for the question: could not the process: magma —> crystallization be irreversible, such that remelting did not reproduce the magma ? There had been attempts to guess the ionic state of a magma, but in reality we do not know that, nor that of the remolten rock. In 1952, x-ray analyses of basaltic glasses were performed in Utrecht for the author, but without any obvious significant result. And for reasons, which have nothing to do with science, my Hekla papers did not reach the distribution which was planned by the Soc. Sci. Isl. and thus did not, to our knowledge, inspire others to take up this question. By now, there are various new data which seem to aid us. We shall first consider suggestive data on silica. We quote from (72): “Diffraction patterns of both silica and germania glasses are consistent with a structure in which nearly all the atoms belong to tridymite-like regions of up to about 20 angstroms or more, that are bonded efficiently together in a manner analogous to that found in twinned crystals” (italics ours). This is a remarkable state in glass. It is largely formed of angstrom-size crystals which, because of their random dis- tribution, make the matter isotropic and translucent in the optical range, and thus glassy by usual definition.
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Greinar (Vísindafélag Íslendinga)

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