Archaeologia Islandica - 01.01.2007, Side 59

Archaeologia Islandica - 01.01.2007, Side 59
Ancient ironmaking in Iceland, Greenland and Newfoundland their approach becomes descriptive. The prescriptive aspect of process metallurgy, expressed by this author, is largely miss- ing (e.g. Espelund 2004b). Out of 51 iron artefacts only 5 contained metallic iron and were studied by SEM analysis. Carbon and sulphur were determined by combustion and absorption. The two nails were as expect- ed high in phosphorus - low in carbon, while the rivet contained 0.12 and a steel sheet fragment 0.36 % C, both low in % P. No less than 15 trace elements were searched for, giving values around 0.01%, which can be regarded as the lower detec- tion limit and therefore disregarded. Only two values for molybdenum 0.061 (nail) (together with 0.60% P) and 0.13 (rivet) (together with 0.076 P) might indicate a special source of ore (:65). The values for the elements Mn and Si were copied from Rosenqvist (1977/85). The lump of cast iron measuring 2.5x2.2x2 cm (Ung- lik and Stewart 1999:20) can hardly be an intended product as no such production took place before the end of the Middle Ages (1300 in Sweden, 1600 in Norway, never in Denmark, Iceland or Greenland). It is more likely that it represents unsuc- cessful smelting at L’Anse aux Meadows, without proper slag control or, alterna- tively, a newer and foreign sample. The value for Si (0.73%) can represent strong reducing conditions and/or entrained slag. Pieces of cast iron have also been encountered by the present author in slag heaps at the Norwegian Roman Age smelting site Myggvollen and at an Even- stad type of furnace in Kása, community ofTolga. The authors also conclude that the cast iron was unintentional (Unglik and Stewart 1999:116). This author selected slag No. 2 (4A505B1-1) for a closer study. If the values for the two iron oxides are added as FeO, the value for the “fayalite ratio” R becomes 2.35, which is a normal figure after extraction of iron. The sum for this sample amounts to 97.4%. An interesting observation from these tables is the com- plete absence of molybdenum in the ore and in slag pieces, indicating that the nail and the rivet mentioned above appear to be of foreign origin. The two nails con- taining 0.60 and 0.56% P can hardly be the result of smelting at L’Anse aux Meadows, as two of the ores presented are so to speak phosphorus-free. Phos- phorus ensured stiffness, useful for a nail, to be driven into wood when a new ship was built, and not to be exposed to any impact later. This is a good expression of professional shipbuilding with access to different materials, characteristic for con- temporary Norway. Among the trace elements the values for molybdenum 0.061% (large nail) and 0.13% (large rivet) deserve special attention. As Mo is fully unex- pected, it has so far not been searched for in my own analyses of Norwegian ores and slags. Geochemical mapping of Scandinavia might reveal the source. According to the Norwegian Geologi- cal Survey there are two areas in South Norway where this element occurs in significant amounts (Korneliussen pers. comm.): Knaben in Setesdal, and Nor- dli near Eidsvoll. Bloomery ironmaking during the Viking Age - Medieval period cannot be excluded in the two areas. This information might reveal the provenance of the iron for the rivets. An analysis by means of microprobe of a sample from a bloom from Skeibrok, community of Lista, County of Vest-Agder UO C 22 615 at the south coast of Norway has shown similar values for molybdenum. By sheer 57
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