Fróðskaparrit - 01.07.2004, Page 88

Fróðskaparrit - 01.07.2004, Page 88
86 MERCURY IN THE FAROE ISLANDS — A REVIEW OF AVAILABLE DATA Introduction Mercury, Hg, is a metal and thus is a natur- al component of our environment. We are familiar with mercury from our every-day life through our dental “silver” fdlings, which are in fact amalgams, where the term amalgam means a mixture of mercury and other metals. This property to blend with other metals at ambient temperature is a special feature of mercury and is the basis for the use of mercury in gold extraction in some areas, an application that leads to at least locally significant pollution. Due to suitable electrochemical and electronic characteristics mercury has also been used in electric equipment and in chlor-alkali production, applications which are now highly restricted in the developed parts of the world. The toxicity of mercury is high- ly dependent on the physiochemical form it occurs in, i.e. the actual species. Pure, metallic mercury for example is more poi- sonous than mercury bound in amalgams, and methylated mercury is more poisonous that mercury in inorganic species. The species are however not static and transi- tion between most chemical forms occur depending on the environment. In the pre- sent review, only inorganic, divalent mer- cury and occasionally methylated mercury or gaseous elemental mercury species are discussed. There are many different mercury sources in the environment but the most im- portant ones are burning of fossil fuels and waste (Pacyna and Keeler, 1995), where stationary combustion' in 1995 of mainly coal accounted for 3A of the global emission (Pacyna and Pacyna, 2000). In addition to this, a large quantity comes from the earth itself as evaporation from the crust and veg- etation and from volcanic activities. Inven- tories indicate that approximately 60% of the mercury entering the atmosphere every year is anthropogenic (AMAP, 1998), where anthropogenic or man-made in this case of a naturally occurring substance sim- ply means that the metal is released to the biosphere through mans activities. Invento- ries based on 1990 and 1995 emission data indicate that there were no major changes in global emission in this period (Pacyna and Pacyna, 2000). There have however, been a decrease estimated to 45% in emis- sions in Europe and North America during this time, but globally this decrease is offset by an almost doubling in the contribution from the Asian sources where the emission which stems from stationary combustion of fossil fuel have increased markedly (Pacy- na and Pacyna, 2000; Pacyna et al., 2001). In the eighties, Nriagu and Pacyna (1988) estimated the amount of mercury being emitted to the atmosphere from anthro- pogenic activities to be equal to that being directly discharged to the sea and approxi- mately half the amount that is deposited on land (Pacyna and Keeler, 1995), implying thus that the other half of the mercury de- posited were stemming from natural pro- cesses. For areas with limited local emission, it is mainly the emissions to air of elemental gaseous mercury which is the most inter- esting part of the overall mercury release, because mercury has a long residence time in the atmosphere and can be transported over long distances until it is eventually de-
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