Fróðskaparrit - 01.07.2004, Page 92

Fróðskaparrit - 01.07.2004, Page 92
90 MERCURY IN THE FAROEISLANDS — A REVIEW OF AVAILABLE DATA Starvsstovan in precipitation collected three times yearly since 1996 (Dam 1998) at Norðuri á Fossum. The locality Norðuri á Fossum is used as the Faroese reference station to the UN/ECE Long-range trans- boundary air pollution programme on Inte- grated Monitoring. At this site, regular analyses of major ions in precipitation are made and results are reported to the UN/ECE Integrated monitoring data centre at the Finnish Environmental Institute. However, mercury in precipitation was measured for the fírst time at the Faroe Is- lands in 2002 as part of a Master of Science program (Daugaard, 2003). Deposition was collected at Elduvík, Eiði, Saksun, Vestmanna and Kirkjubøur for 6 periods each of 3 weeks duration cov- ering the period June to October 2002. The sum mercury deposition during the 6 week period varied from 5,3 ng to 10,9 ng Hg. A distinct negative correlation was found be- tween the amount of deposition and the concentration of mercury in deposition, in- dicating that the washout of mercury from the atmosphere were most intense during the fírst mm of the rain-shower. (Daugaard, 2003). The terrestrial and freshwater environment Peat and Soil Peat core samples were collected in May 2000 from the two peat-bogs á Mýrunum in Vestmanna and the Klovin bog in Vatns- oyrar (Roos et al., 2001). The samples from á Mýranar were analysed for mercury and dated in order to study the changes in mer- cury fluxes with time. The results (Shotyk et al., 2003; 2004) indicated that the major part of mercury in the peat has been trans- ported through the atmosphere. Several layers of ash in the peat cores were noticed and these seemed to originate from Ice- landic volcanoes. Although it was pre- sumed that some volcanoes have had a cer- tain influence on the mercury supply to these samples, some very high values in the peat for the time-period around 1950 could not be explained by natural sources alone. Besides mercury, high values of bromide and chloride were found which showed the impact of sea spray on the peat. Despite the cutting of peat it appeared that the time pe- riods were well preserved (Goodsite et al. 2002). Shotyk et al. (2004) declared that the measured mercury values were higher than those found in other Nordic countries and that the results indicated that the natural background flux of mercury to the Faroes was always elevated, compared to conti- nental bogs. Superimposed on these elevat- ed natural fluxes, however, they found a much greater Hg flux in samples from the last two centuries. The large total mercury peak (498 ng Hg/g dw) at á Mýranar were found in depths between 5 cm and 6 cm, and was higher than what could reasonably be explained by geo-chemical mechanisms or natural input. Data are available on a number of metals and minerals in soil and basalt (Rasmussen and Noe-Nygaard, 1969; Joensen and Vestergaard 1995; Mikkelsen et al., 2002) but few data are available on mercury, (Table 1).
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