Fróðskaparrit - 01.07.2004, Page 93

Fróðskaparrit - 01.07.2004, Page 93
KYKSILVUR í FØROYUM - EIN GJØGNUMGONGD AV TØKUM DÁTUM 91 Fig. 1. Mercury in soil profiles from Norðuri á Fossum, 2002. (Heilsufrøðiliga Stan’sstovan, unpubl. In 2002 two soil profiles were collected at Norðuri á Fossum. The soil profiles were cut in segments of 1,5 cm starting at 1 cm below the surface, and analysed for mer- cury as well as a selection of other metals (Al, As, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, V and Zn) as well as the dry matter content (Heilsufrøðiliga Starvsstovan). The results of the mercury analyses are given in (Fig. 1) as a function of the upper level of profile segment depth. There are significant differ- ences in the inercury concentrations among the two profiles even though they were tak- en only approx. 50 m apart in an area that is not influenced by local pollution sources. The profile no. 3 was taken from the east- ern side of the river Dalá, in an area where deptli segment, Sampling cm Hg Norðuri á Fossum, no. 3, peat 1-9 0,54 Norðuri á Fossum, no. 6, peat 1-9 0,23 Reference sitea 0-20 0,15 Heilsufrøðiliga Starvsstovan, 1991 Table 1 Mercury (mg/kg dw) in peat cores taken Norðuri á Fossum in 2002 and at a reference site in 1991. regular wet deposition collection has been ongoing since 1996. The profile no. 6 was taken from the western side of Dalá, in a moist and bog-like area. The soil from the two sites have not been characterised apart from the metal analyses indicated in the parenthesis above. When comparing medi- ans of metal concentrations in the two pro- files, it appears that there are three metals which are markedly different in the profile no. 3 compared to no. 6, they are mercury, vanadium and arsenium, where the two fist mentioned are elevated and the last men- tioned is lowered. The median mercury concentration in the profile no. 3 is more than twice as high as the one in the profile from the more moist area. In the surface layer (-1 to 2,5 cm) , the concentration of mercury in the profiles no. 3 and 6 are 0,90 and 0,48 mg/kg dw respectively. The tran- sition from organic soil to mineral soil oc- curred at a depth of approx. 6 cm in the pro- file no. 3. Diagenetic processes may relo- cate metal-ions in a sediment or moist soil environment. The process is driven by re- dox-reactions and it is known that man-
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