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Jökull - 01.12.1986, Qupperneq 40

Jökull - 01.12.1986, Qupperneq 40
above, the Maelifell picrite basalt has a whole-rock composition rich in MgO (26 wt.%), whereas the quenched glass composition has a low MgO content (8.8 wt.%). Based on experimental petrology, field evi- dence and the general primitive characteristics of picrites, Clarke (1970), Reid & Woodes (1978), Clarke & O’Hara (1979), Elthon (1979) and Maaloe & Jakobsson (1980) have made a strong case for the existence of a high-MgO basic liquid (18-30 wt.%). Further confirmation of the existence of a high-MgO liquid has been manifested by the primitive character- istics of the Maelifell picrite basalt and by the calcu- lation of the two end-members involved in the mix- ing; one end-member is inferred to be primitive (MgO approximately 18 wt.%). Flowever, the Maelifell whole-rock composition has a much higher MgO (approximately 26 wt.%) content than do these calcu- lated end-members (18 and 13 wt.%). This can only indicate that the magma has picked up olivine pheno- crysts, as will be shown below. By combining whole- rock composition, mineralogy, mineral chemistry and textural evidence, the following appears to be the most reasonable model to explain the above mixing. The Maelifell volcano is probably underlain by a complex plumbing system which allows magma from the mantle to ascend to the surface. Magma must have been caught in a trap (magma chambers) on the way to the surface where cooling and crystallization caused differentiation. This magma was relatively evolved and crystallized olivine (Fo86_89) that accumulated at the base. Plagioclase (An85_89, present as inclusions) crystallized as well. This resulted in a more evolved melt remaining in the upper part of the chamber. Fresh pulses of upper-mantle-derived melt arrived, as indicated by the primitive characteristics of one of the ealculated end-members. This melt carried primitive olivine (FOg9_91), Cr-spinel and Cr-Al-endiopside with a high Cr content (averaging > 1 wt.% Cr703). Part of the cumulate-olivine- plagioclase-bearing melt mixed with this primitive melt, resulting in the occurrence together of reversely zoned olivine (group I) and normally zoned olivine (group II), and erupted as subglacial picrite basalt. It has been suggested that hot picritic parental liquids are too dense, upon injection into a magma chamber, to mix directly with the residual (or evolved) liquid of the chamber (Sparks et al. 1980, Stolper & Walker 1980, Huppert & Sparks 1980). Several recent publications, including those of O’Hara & Mathews (1981), Huppert et al. (1982), Sparks (1983), Bell (1983) and Fitton et al. (1983), show, however, that mixing must take place with time and that commonly only part of the fluids mix. Grön- vold & Óskarsson (pers. comm. 1983) do not find the reversely zoned olivine in their samples of Maelifell picrite basalt from a nearby area, which supports mix- ing on a local scale at Maelifell. FIELD WORK AND ANALYTICAL TECHNIQUES Detailed petrolocical study was carried out on a 4 kg sample. This involved four thin sections, four microprobe sections and XRF analyses for major and trace elements. XRF ANALYSES INSTRUMENT: Phillips PW1400 spectrometer with Rh target. Major elements analyzed using fused beads, dilution ratio 1:5, diluted with lithium tetraborate. Fused using Claisse Fluxer. Analysis procedure and correc- tions outlined in the Geochemistry Laboratory, De- partment of Geological Sciences, XRF Circular # 1. ELECTRON MICROPROBE ANALYSES The mineral and the glass analyses were performed using the CAMEBAX electron microprobe at McGill University. Stoichiometric silicates were employed as standards and ZAF corrections were made on the data. The accelerating voltage and beam current used were 15 kV and 5 nÁ respectively. One to twenty spots (an average of 5) in each crystal were analyzed depending upon homogeneity. The same standards used for the minerals were used for the glass analyses. Following analyses were done on the microprobe; 196 olivine anal. (16 grains of group I, 15 of group II), 19 plagioclase anal., 31 pyroxene anal., 6 spinel anal. and 6 glass anal. ACKNO WLEDGEMENTS This paper summarizes part of main results of the authors M.Sc thesis. I would like to acknowledge the help of my professors and advisors R.F. Martin and D.M. Francis at McGill University Montreal Canada. Kristján Saemundsson at the National Energy Auth., Sveinn P. Jakobsson at the Icelandic Museum of Natural History, Karl Grönvold and Niels Óskarsson at the Nordic Volcanological Institute are thanked for reading an early draft and for many helpful sug- gestions. 38
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