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Jökull - 01.12.1986, Síða 25

Jökull - 01.12.1986, Síða 25
Fig 14. Origin of the chemical con- tents of the groundwater on the Reykjanes peninsula. Storm carried marine salts, cations and silica from the bedrock and geothermal influx are the chief sources of the chemical contents of the groundwater (Sigurðs- son 1985). Mynd 14. Uppruni efna i grunnvatninu. Sœlöður, uppleyst efni úr berginu og jarðhitapœkill frá há- hitasvœðunum eru uppistaðan í efna- innihaldi grunnvatnsins (Freysteinn Sigurðsson 1985). what varying ratios, depending on the season and the climatic conditions. The chloride content in the pre- cipitation is higher in winter than in summer, and highest in the wet winter storms. As the storms are the result of cyclones passing from the southwest and causing southerly winds, the chloride content is much higher on the southern side of the Reykjanes penin- sula than on its northern side. In the spring areas at the northern border ( Heiðmörk, Straumsvík) the chloride content is about 10 ppm or less; on the northern side of the western peninsula it is 20 — 30 Ppm and in the NW-part of the Lágasvæði area it is 40-45 ppm. It increases rapidly towards the Svarts- engi geothermal field. In the zone of off-flow from Svartsengi it is 200 ppm CI” or more, due to the in- fluence of the geothermal water. Interaction between the rocks and the (cold) groundwater leads to an overall increase in silica and the earth-alkaline and alkaline ions. Typical values for silica are about 15 ppm (table 1). Lower values seem to be found in water with a “local” character, perhaps indicating a relatively short stay in the ground, while notably higher values are interpreted as indications of a geothermal influence (fig. 15). In geothermally affected water the variation in the concentration of the cations is usually large while it increases gradually and regularly with the chloride content in the “regional” water. If the values for the cations are corrected according to the chloride content, the basic “rock” values are similiar to those found elsewhere in the Neo-volcanic zones (Sigurðsson, unpublished preliminary review). Mixing of freshwater with geothermal fluids leads to an increase in temperature and total chemical con- tent. The chloride content in the geothermal fluid of Svartsengi and Eldvörp corresponds approximately to a % seawater mixture but in a number of aspects the chemical composition is different from a diluted mix- ture of pure seawater (Hauksson 1980, Bjarnason 1984). There is an enormous increase in silica, some increase in calcium and potassium and a drastic re- duction in magnesium and sulphate. These differences make it in many cases possible to distinguish between heated seawater and true geothermal brine, as a com- ponent in the freshwater. Both types are found in the off-flow area from Svartsengi, but heated seawater seems to be dominant (fig. 15). The freshwater flowing towards the coast in Grindavík and west of there — probably all the way west to Reykjanes proper — has a temperature of 7—10°C and a chloride content of 200 ppm or higher and a composition resembling diluted seawater. According to various international standards this water is not potable, but it seems to be excellent for fishfarming. At the coast the salinity still increases, due to tidal effects. The tidal waves can be measured some km in- land (Ingimarsson & Elíasson 1980, Orkustofnun & Vatnaskil 1984) and affect the transition layer at the bottom of the freshwater layer in the western penin- sula. The amplitude of the tidal waves soon decreases to some centimetres or even some millimetres with increasing distance from the shore, but the waves are still big enough to change the water at a given point at the bottom of the freshwater layer twice a day. Some 23
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