Jökull


Jökull - 01.01.2009, Page 54

Jökull - 01.01.2009, Page 54
J. T. Andrews and J. Harðardóttir val of ca. 6 cm at the beginning and end of each u- channel. Hence, for a 3 m JM96 core we have deleted 36/300 readings per core, whereas we only deleted 24/300 readings on the 150 cm sections of B997. The magnetic measurements performed on the u-channels involved natural remanent magnetization (NRM) measurements, including several demagne- tization steps (Appendix I). Volume susceptibility (k"10"5 SI units) was measured (not always success- fully) using a Bartington loop separate from the mag- netometer (Thomas et al., 2003). Anhysteretic rema- nence (ARM) was imparted with a 100 mT AF field and 0.5 mT DC field. The ARM was measured af- ter stepwise AF demagnetization (Appendix 1). Fi- nally, isothermal remanent magnetization (IRM) was induced with a 1.0 T strong magnetic field. The u- channels were then subject to several demagnetization steps. However, the strength of the signal frequently overloaded the system; for this reason we have ex- cluded evaluation of the IRM data. We focus on parameters that describe various as- pects of the sediment- and paleo-magnetic character of these shelf sediments. For example, if the miner- alogy is dominantly magnetite then the susceptibil- ity of ARM (kARM) when normalized with volume magnetic susceptibility (k) is a measure of the domain grain size of magnetic minerals, and is often referred to as “magnetic grain size” (higher kARM/k values in- dicate finer magnetic grain size (King and Channell, 1991)). ARM(J0)/ARM(J20) has also been shown to be closely correlated with grain-size of the bulk sedi- ment in a core from the North Iceland shelf (Andrews et al., 2003). The NRM data gives information on the declination, inclination, and intensity of the magnetic field at the time of deposition (or shortly thereafter). The characteristic remanence intensity of the sedi- ment is, however, also affected by the concentration and type of available ferrimagnetic minerals; thus the intensity measurements are normalized with parame- ters such as MS, ARM, or IRM (Lund and Schwartz, 1999). Quantitative X-ray diffraction (XRD) of the <2 mm sediment fraction has been carried out on 3 of the East Greenland cores and 5 from Iceland (Andrews and Eberl, 2007). Weight % estimates of quartz, mag- netite, hematite, and volcanic glass have been deter- mined (Appendix 2). Magnetite, plus its close relative maghemite, varied on average between 2.5 and 7 wt% whereas hematite is much lower. The higher values of quartz in East Greenland sediments compared to Iceland (Appendix 2) represent proximal glacial ero- sion of Precambrian Shield rocks of Greenland and/or transport of quartz in sea ice from the Arctic Basin, compared to the more variable drift ice history of Iceland. DATA PROCESSING AND ILLUSTRATIONS Our primary objective is a regional comparison of the data and we do not present the down core data (the raw data will be deposited in the NOAA Paleoclimate databases – www.ngdc.noaa.gov/paleo/data.html). Downcore data along a fjord/shelf transect has been published for the Vestfirðir area (sites B997-339 to -336, Figure 1 and Table 1) (Andrews et al., 2008). We have chosen the Exploratory Data Analysis ap- proach for measures of central tendency and disper- sion, namely the median and pseudo-sigma (Hamil- ton, 1990); this follows previous arguments in deal- ing with the sediment properties from many of the same cores (Andrews et al., 2002a). The median is a more conservative measure of central tendency than the mean, as skewness or outliers do not influ- ence it. Pseudo-sigma is defined as the interquartile range/1.34 (Hamilton, 1990). Finally, in order to com- pare variability amongst the parameters we calculate a coefficient of variability (CV%) as: (median/pseudo sigma)*100. CV% is a statistic designed to normalize the usually positive correlation between means and standard deviations because the latter is frequently correlated with the average (Hamilton, 1990). The tabulated data (medians, CV% etc.) can be obtained from the first author. We used an Excel®program (Mazaud, 2005) to calculate the maximum angular deviation (MAD) re- sulting from the AF demagnetization steps, the me- dian destructive field (MDF mT) for demagnetization, and to derive an estimate of the characteristic declina- tion and inclination (Kirschvink, 1980) (Appendix 2). 54 JÖKULL No. 59
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