Fróðskaparrit - 31.12.2000, Side 169

Fróðskaparrit - 31.12.2000, Side 169
KANNINGAR AV KYKSILVRI OG ORGANOKLORIDUM I EINSTØKUM HAVSUGDJORUM I FØROYUM 173 lation cocfficient (0.84) for Mirex was found in relation to p,p’-DDE, and, when performing the correlation analyses of Mirex concentration vs. the DDT group for the males and the females separately, it ap- peared that the correlation was weaker in the males than in the females. The correla- tion between the Mirex and the DDT com- pound groups is thus different in the two whale species, as well as between the whales and the seals. The very same white-sided dolphin indi- viduals that were analysed for organochlo- rines, were also analysed for mercury, and, thus, correlation analyses were performed on females and males separately. The analyses revealed negative correlations be- tween mercury and the organochlorines for the females and no positive correlations for the males. Quality Assurance - Quality Control The general quality control protocol of the laboratories includes duplicate analyses on 10% (POPs) or 15% (Hg) of the samples. The precision of the mercury analyses is given as a relative standard deviation be- tween doublet analyses of the samples (Table 20). A summary of the precision re- port for the PCB analyses is given in Table 15. Tables 16 and 17 summarise the results of the precision analyses, exemplified with the Sum Chlordane and Sum DDT, as a per- cent standard deviation. For toxaphene analyses, the overall mean standard devia- tion of the 14 duplicate analyses was 4%. The individual results are provided in Table 18. 1 Mirex (empirical formula C|oCl,2) is also known as a hexachloropentadiene dimer. 2 Sum DDT = p,p’-DDT, p,p’-DDE, p,p’-DDD, o,p’- DDT, o,p’-DDE and o.p’-DDL). Acknowledgements This work was funded by a grant from DANCEA, as part of the Arctic Environmental Program. Thanks to Bjarni Mikkelsen for sharing the seal samples, thus making the seal analyses possible. Thanks also to our former secretary for doing the white-sided dolphin sam- pling and to the laboratory staff for their meticulous analysis work. Thanks also to Dorete Bloch for com- ments on an earlier version of this article. References Aguilar, A., Jover, L. and Borrell, A. 1993. Hetero- geneties in organochlorine profiles of Faroese long- finned pilot whales: indication of segregation be- tween pods? In: Donovan, G.P., Lockyer, C.H. and Martin, A.R., (eds.) Biology of Northern Hemi- sphere Pilot Whales. Report of the International Whaling Commission (Special Issue 14): 359-367. AMAP 1998. AMAP Assessment Report: Arctic Pollu- tion Issues. Arctic monitoring and Assessment Pro- gramme (AMAP), Oslo, Norway. xii: 859 pp. Andersen, L.W. 1993. Further studies on the population structure of the long-finned pilot whale, Globi- cephala melas, off the Faroe Islands. In: Donovan, G.P., Lockyer, C.H. and Martin, A.R. (eds.) Biology of Northern Hemisphere Pilot Whales. Report ofthe International Whaling Commission (Special Issue 14): 219-231. Andersen, L.W. and Siegismund, H.R. 1994. Genetic evidence for migration of males between schools of the long-finned pilot whale, Globicephala melas. Marine ecology progress series. Oldendorf 105,1 -7. Bloch, D. and Fuglø, E. 1999. Villini súgdjór í Útnorðri. Føroya Skúlabókagrunnur and Føroya Náttúrugripa- savn. Bloch, D., Lockyer, C. and Zachariassen, M. 1993. Age and growth parameters of the long-finned pilot whale off the Faroe Islands. In: Donovan, G.P., Lockyer, C.H. and Martin, A.R. (eds.) Biology of Northern Hemisphere Pilot Whales. Report of the International Whaling Commission (Special Issue 14): 163-208. Boon, J.P., Amhem, E.v., Jansen, S., Kannan, N., Pet- rick, G., Schulz, D., Duinker, J.C., Reijnders, P.J.H.
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